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Lithium-ion (Li-ion) Battery

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What is a Lithium-ion (Li-ion) Battery?

  • A Lithium-ion (Li-Ion battery) is a type of rechargeable battery that uses lithium compounds as one of the electrodes.
  • In 1985, Akira Yoshino developed the first prototype.

Lithium Battery Cell

Lithium battery cell
Lithium battery cell
  • Each Lithium battery cell has essentially three components.
    • A Positive electrode – (Lithium cobalt oxide, or LiCoO2).
    • A Negative electrode – (Carbon).
    • A Separator Electrolyte – most commonly used (lithium salt, such as LiPF6) in an organic solution.
    • In addition, lithium-ion batteries incorporate other elements that improve their performance and safety: a temperature sensor, a voltage regulator circuit and a state-of-charge monitor.
  • When the battery is charged, lithium ions flow from the positive electrode to the negative electrode through the electrolyte and attach to the carbon.
  • During discharge, the lithium ions return from the carbon to the LiCoO2.

Applications of Li-ion Battery

  • Emergency power systems – server farms, the batteries of a UPS (Uninterruptible Power Supply).
  • Solar energy storage: Solar energy storage is intermittent, and these batteries are best suited to solar panels because they charge fast.
  • Consumer electronics and mobile devices: Allows for ever-increasing miniaturisation.
  • Disability assistance: electric wheelchairs, stairlifts or motorised prostheses.

Advantages of Li-ion battery

  • High Efficiency: Charge/discharge efficiency ~90–95%; less energy wasted as heat, making them suitable for renewable integration (solar/wind).
  • High Energy Density: Lithium-ion batteries are top performers in energy storage, holding far more energy per unit weight compared to lead-acid batteries (260–270 Wh/kg vs. 50–100 Wh/kg).
  • Lightweight: On average, they weigh 50–60% less than traditional batteries, making them ideal for compact devices like smartphones and e-readers.
  • Longer lifecycle: Lithium-ion batteries can endure ~2,000 charge-discharge cycles, providing a longer lifespan of 8-10 years.
  • Long-Term Performance: Even after ~200 cycles, lithium batteries retain around 80% of their rated capacity, ensuring consistent performance over time.
  • Low Self-Discharge: Lithium-ion cells lose only ~5% charge initially and just 1–2% per month thereafter, far lower than most other rechargeable batteries.

Problems with Lithium-ion Batteries

  • Energy density is still lower compared to petrol.
  • Requires higher protection circuit to prevent thermal runaway if stressed.
  • Performance declines with time.
  • At freezing temperatures (zero degrees Celsius), quick charging is not possible.
  • Lithium-ion battery packs degrade significantly more quickly when exposed to heat.
  • Environmental concerns are primarily related to the mining of lithium.
  • The liquid electrolyte used in EV batteries is highly flammable.
  • Energy density is the amount of energy the battery can store with respect to its mass.
  • Power density is the amount of power that can be generated with respect to its mass.

Sodium-Ion and Lithium-Ion Batteries: A Comparison

  • Sodium-ion batteries are a promising alternative to lithium-ion batteries – currently the most widely used type of rechargeable battery.

Sodium-Ion Batteries

Lithium-Ion Batteries

  • Sodium is more than 500 times more abundant than lithium. Also extracted from seawater at a low cost.
  • Lithium availability is limited to a few countries, which is why prices have risen more than seven-fold since 2021.
  • Sodium is more environmentally friendly and can be transported at zero volt, making it safer.
  • Less environmentally friendly than sodium and must be always stored with a minimum charge, increasing fire risks.
  • A Sodium-ion battery uses aluminum which is cheaper than copper.
  • Lithium-ion battery uses copper, which is three or four times more expensive than aluminum used on sodium batteries.
  • Sodium-ion battery has a higher operating temperature range. Can be used in more extreme temperatures without the risk of thermal runaway.
  • Lithium-ion battery has lower operating temperature range and can cause fire if operated in higher temperatures.
  • Sodium-ion battery charges faster than lithium-ion variants and have a three times higher lifecycle.
  • Slow charge rate and smaller lifecycle compared to sodium-based batteries.

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